贺晓慧博士，1966年出生，南昌大学二级教授，博士生导师，华南理工大学校外兼职博士生导师，曾任材料科学与工程学院高分子材料科学与工程系主任。入选2007年江西省新世纪百千万人才工程；2007年和2009年江西省中青年高分子材料学科带头人；2013年第十七批江西省主要学科学术和技术带头人。2004年毕业于中山大学高分子化学与物理专业，获理学博士学位，师从伍青教授；2006-2008 年在南昌大学材料物理与化学博士后流动站完成博士后研究工作出站，师从陈义旺教授；2009-2010 年赴美国麻省理工学院(MIT)化学系做访问学者，师从2005年诺贝尔化学奖得主理查德·施罗克(Richard R. Schrock)教授。目前主持国家自然科学基金项目5项，江西省主要学科学术和技术带头人培养计划项目1项，江西省自然科学基金项目5项，江西省教育厅科技重点项目3项；以通讯作者/第一作者在国际高水平的SCI源刊，如Polym. Chem.，J. Power Source，Organometallics，Macromolecule，J. Polym. Sci., Part A: Polym. Chem.，Macromol.Chem. Phys. RSC Adv.，Int. J. Hydrogen Energy., Polymer等上发表研究论文80余篇。获授权国家发明专利10项。共培养研究生46名，其中博士研究生6名。获得江西省自然科学奖二等奖1项，江西省科技进步奖一等奖1项。

研究方向

本课题组主要聚焦于烯烃配位聚合金属催化剂及功能聚环烯烃、燃料电池离子交换膜材料、固态锂离子电池聚电解质材料、高性能聚酰亚胺材料等领域的理论与应用研究。

承担科研项目

1.国家自然科学基金地区项目，高温固态聚苯并降冰片二烯咪唑离子液体及其复合电解质膜的制备与锂离子传输机制，51963015，主持2020-2023，41.0万元，在研。

2.国家自然科学基金面上项目，基于功能环烯烃共聚的C-C桥联[N^O]配位单金属限制几何构型催化剂一步原位构筑、构-效关系及机理，21674045，主持，2017-2018，32.0万元，结题。

3.国家自然科学基金地区项目，新型长效阻醇加成型聚降冰片烯基碱性阴离子交换膜的制备机理及其离子传输、阻醇、长期稳定性强化机制，51463014，主持，2015-2018，48.0万，结题。

4.国家自然科学基金地区项目，空间立体几何构型α-酮亚胺配体后过渡金属催化剂合成及催化极性环烯烃共聚合，21164006，主持，2012-2015，53.0万元，结题。

5.国家自然科学基金地区项目，环烯烃及其衍生物催化配位聚合及聚合物光学性能研究，50663002，主持，2007-2009，28.0万，结题。

6.江西省主要学科学术和技术带头人培养计划项目，高效共价键合纳米二氧化硅负载新型立体几何构型二亚胺镍(II)催化剂合成及其应用催化制备纳米复合聚降冰片烯材料，20133BCB22003，主持，2013-2015，20万元，结题。

7.光学级PMMA亚克力高端装饰板材制备及产业化,企业合作项目，主持，2020-2021，50.0万，在研。

8.

代表性学术成果

1.Xiaohui He*, Jianhua Zou, Yufei Wen, Bin Wu, Xiujing Zang, Jiahao Deng,Zengwei Qin, Guoxiao Yang, Jiang Xu, Defu Chen，Preparation and performance of bisimidazole cationic crosslinked addition-type polynorbornene based anion exchange membrane，International Journal of Hydrogen Energy,2022,47,69-80.(他引4次,IF: 4.417)

2.Xiaohui He* ; Jianhua Zou; Yan Guo; Kai Wang; Bin Wu; Yufei Wen; XiujingZang; Defu Chen; Synthesis of halogenated benzonorbornadiene monomer andpreparation of self-crosslinking bisimidazole cationic functionalizedbenzonorbornadiene triblock copolymer anion exchange membrane, Polymer, 2021, (218): 123535-123544.

3．Xiaohui He*,Yan Guo, Xueqi Chen, Bin Wu, Jianhua Zou, Yufei Wen, Defu Chen,Synthesis of MWNTs/SiO2 supported nickel and palladium complexes and their application as catalysts for cyclic olefins polymerization，Journal of Organometallic Chemistry,2021, 949,121953. DOI: 10.1016/j.jorganchem.2021.121953.

4. Cheng, Changwen; Xiaohui He*; Huang, Shengmei; Zhang, Feng; Guo, Yan;Wen, Yufei; Wu, Bin; Chen, Defu; Novel self-cross-linked multi-imidazoliumcations long flexible side chains triblock copolymer anion exchange membranebased on ROMP-type polybenzonorbornadiene, International Journal of HydrogenEnergy, 2020, 45(38): 19676-19690.

5. Xiaohui He* ; Changwen Cheng; Shengmei Huang; Feng Zhang; YapengDuan;Chuanyi Zhu; Yan Guo; Kai Wang; Defu Chen; Alkaline anion exchange membraneswith imidazolium-terminated flexible side-chain cross-linked topologicalstructure based on ROMP-type norbornene copolymers , Polymer, 2020, 195(122412): 1-9.

6. Feng Zhang; Xiaohui He* ; Changwen Cheng; Shengmei Huang; Yapeng Duan;Chuanyi Zhu; Yan Guo; Kai Wang; Defu Chen; Bis-imidazolium functionalizedself-crosslinking block polynorbornene anion exchange membrane , InternationalJournal of Hydrogen Energy, 2020, 45: 13090-13100.

7. Shengmei Huang; Xiaohui He* ; Changwen Cheng; Feng Zhang; Yan Guo; DefuChen; Facile Self-crosslinking to Improve Mechanical and Durability ofPolynorbornene for Alkaline Anion Exchange Membranes , International Journalof Hydrogen Energy, 2020, 45: 13068-13079.

8. Shengmei Huang, Xiaohui He*, Yan Guo, Defu Chen, Tuning the effects of N1 substituents on the 2-methylimidazolium functionalized polynorbornene alkaline anion exchange membranes, Polymer, 2020, 206, 122883.

9. Xiaohui He*, Yapeng Duan, Yan Guo, Kai Wang, Bin Wu, Yufei Wen, JianhuaZou, Chuanyi Zhu, Shengmei Huang, and Defu Chen, Hexacoordinated NickelCatalysts Containing salicylaldbenzhydrylimine Ligand and TetrahydrofuranHeterocycle: High Catalytic Activity and High 1-Hexene Insert Ratios for Norbornene(Co)polymerization, Journal of Organometallic Chemistry,2020, 121241. DOI:10.1016/j.jorganchem.2020.121241.

10. Xiaohui He*,Chuanyi Zhu, Shengmei Huang, Yapeng Duan, Feng Zhang,Changwen Cheng, Kai Wang, Yan Guo, Bin Wu, Yufei Wen, Jianhua Zou, and DefuChen, Nickel Complexes Bearing Different Electron Groups on SubstitutedSalicylaldnaphthylmethyleneimine Ligands: Syntheses and Their CatalyticPerformance for (Co)polymerization of Norbornene, Applied OrganometallicChemistry,2020,e5625. DOI: https://doi.org/10.1002/aoc.5625.

11. Xiaohui He*，Suli Wang, Yingping Yang, Guangshui Tu, Feng Zhang, ShengmeiHuang, Yapeng Duan, Chuanyi Zhu, Changwen Cheng, Defu Chen, C–C bridgedNi(II) complexes bearing β-keto-9-fluorenyliminato ligands prepared by different insitu bonding mechanisms and their use in catalytic (co) polymerization of norborneneand styrene, Applied Organometallic Chemistry,2019, 33 ，e4694. DOI:10.1002/aoc.4694.

12. Xiaohui He*, Guangshui Tu, Feng Zhang, Shengmei Huang, Changwen Cheng,Chuanyi Zhu, Yapeng Duan, Suli Wang, Defu Chen,Bis-(salicylaldehyde-benzhydrylimino)nickel complexes with different electron groups: crystal structure and their catalytic properties toward (co) polymerization ofnorbornene and 1-hexene, RSC Advances,2018. 8, 36298-36312.

13. Xiaohui He*, Xiong Jiang, Zijie Wang, Yingjiao Deng, Zhilong Han, YingpingYang, Defu Chen, Cross-linked hydroxyl-conductive copolymer/silica compositemembranes based on addition-type polynorbornene for alkaline anion exchangemembrane fuel cell applications, Polymer Engineering & Science,2018, 58(1),13-21.

14. Xiaohui He*, Yingjiao Deng, Xiong Jiang, Zijie Wang, Yingping Yang, ZhilongHan, Defu Chen, Copolymerization of norbornene and butyl methacrylate at elevatedtemperatures by a single centre nickel catalyst bearing bulky bis(α-diimine) ligandwith strong electron-withdrawing groups, Polymer Chemistry,2017, 8, 2390-2396.

15. Xiaohui He*, Yingping Yang, Suli Wang, Zhilong Han, Guangshui Tu, FengZhang, Shengmei Huang, Zijie Wang, Defu Chen, Synthesis ofbis-(benzocyclohexan-ketoimino) Ni(II) with different electron groups and theircatalytic copolymerization of norbornene and polar norbornene，RSC Advances, 2017,7, 48745-48753.

16. Xiaohui He*, ZijieWang, Weihua Zhou, Xiong Jiang, Zhilong Han, Defu Chen,Imidazolium-functionalized norbornene ionic liquid block copolymer and silicacomposite electrolyte membranes for lithium-ion batteries, Journal of AppliedPolymer Science,2017, 134(22), DOI: 10.1002/APP.44884.

17. Xiaohui He*, Zhilong Han,Yingping Yang, Suli Wang, Guangshui Tu, Feng Zhang, Shengmei Huang, Zijie Wang, Defu Chen, The preparation and application of a ROMP-type epoxy-functionalized norbornene copolymer and its hybrid alkaline anion exchange membranes, RSC Advances,2017, 7(88), 55977-55985.

18. Ping Huo, Wanyun Liu, Xiaohui He*, Yiwang Chen*, Symmetric Single Nickel Catalysts Bearing Bulky Bis(α-Diimine) Ligand: Synthesis, Characterization, and Electron-Effects on Copolymerization of Norbornene with 1-Alkene at Elevated Temperarure, Journal of Polymer Science Part A: Polymer Chemistry, 2016. 54,3495-3505.

19. Jianwen Tian, Xiaohui He*,*Jingyin Liu, Xiaodan Deng, Defu Chen, alladium(ii)and copper(ii) chloride complexes bearing bulky α-diimine ligands as catalysts fornorbornene vinyl-addition (co)polymerization, RSC Advances.2016. 6(27),22908-22916.

20. Xiaohui He*, Jingyin Liu, Hongyu Zhu, Yan Zheng，Defu Chen, Novel quaternary mmonium functional addition-type norbornene copolymer as hydroxide-conductive and durable anion exchange membrane for direct methanol fuel cells, RSC Advances,2015, 5(78), 63215-63225.

21. Jianwen Tian, Xiaohui He*, Jingyin Liu, Xiaodan Deng，Defu Chen, Synthhesis

of well defined C-C bridged Ni(II) complexes bearing β-ketoiminato-fluorene ligands

by bifluorenyl in situ coupling and application for norbornene (co)polymerization,

RSC Advances. 2015. 5(76), 61851-61860.

22. Ping Huo, Wanyun Liu, Xiaohui He*, Zhenhong Wei,Yiwang Chen*, Substituent

effects and activation mechanism of norbornene polymerization catalyzed by

three-dimensional geometry α-diimine palladium complexes, Polymer Chemistry,

2014, 5, 1210-1218.

23. Ping Huo, Wanyun Liu, Xiaohui He*, Yiwang Chen*, Norbornene/n-butyl methacrylate copolymerization over α-diimine nickel and palladium catalysts supported on multiwalled carbon nanotubes, Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52(22), 3213-3220.

24. Lu Chen, Zhichuan Zhong, Chao Chen, Xiaohui He*, Yiwang Chen*,N,O-chelating bidentate Ni (II) and Pd (II) complexes for copolymerization ofnorbornene and norbornene ester, Journal of Organometallic Chemistry,2014, 752,100-108.

25. Jianwen Tian, Hongyu Zhu, Jingyin Liu, Defu Chen, Xiaohui He*, Pd(II)complexes bearing di- and monochelate fluorinated β-ketonaphthyliminato ligand andtheir catalytic properties towards vinyl-addition polymerization and copolymerizationof norbornene and ester-functionalized norbornene derivative, Applied Organometallic Chemistry,2014, 28(9), 702-711.

26. Ping Huo, Wanyun Liu, Xiaohui He*, Yiwang Chen*, Novelpoly(benzonorbornadiene) derivatives prepared by a three-dimensional geometrybimetallic nickel catalyst with good processability for electrospinning,Macromolecular Materials and Engineering,2014, 299(4), 470-477.

27. Ping Huo, Wanyun Liu, Xiaohui He*, Hongming Wang, Yiwang Chen*, Nickel(II) Complexes with Three-Dimensional Geometry α-diimine Ligands: Synthesis and Catalytic Activitytoward Copolymerization of Norbornene, Organometallics,2013, 32(8), 2291-2299.

28. Xiaohui He*, Yan Zheng*, Hongli Yao, Yiwang Chen*, Defu Chen, HybridNetwork Sulfonated Polynorbornene/Silica Membranes with Enhanced ProtonConductivity by Doped Phosphotungstic Acid, Fuel Cells, 2014, 14(1), 26-34.

29. Xiaohui He*, Meiping Hu, Yi Wang Chen*, Defu Chen. Hybrid polyelectrolytes based on stable sulfonated polynorbornene with higher proton conductivity and lower methanol permeability. Journal of Power Sources,2013, 242(35): 725-731.

30. Hongli Yao, Xiaohui He*, Lu Chen, Yiwang Chen*, Defu Chen, Vinyl-additiontype norbornene copolymers containing flexible spacers and sulfonated pendantgroups for proton exchange membranes, Journal of Applied Polymer Science,2013,128(6), 3540-3547.

31. Lie Chen, Xiaofeng Wang, Xiaohui He*, Shufang Liu, Yiwang Chen*, WeihuaZhou, Vinyl-addition Type Norbornene Copolymer Containing Sulfonated BiphenylPendant Groups for Proton Exchange Membranes, Journal of Applied PolymerScience, 2013, 127(3), 2280-2289.

32. Meiping Hu, Xiaohui He*, Yiwang Chen*, Defu Chen, Sulfonated Copoly(norbornene)s Bearing Sultone Pendant Groups and Application as ProtonExchange Membranes Candidates, Journal of Polymer Research.2012, 19:9977.

33. Xiaofeng Wang, Jianqiang Hu, Ting Hu, Yanyun Zhang, Yiwang Chen*, WeihuaZhou, Shuqin Xiao, Xiaohui He*, Crosslinked electrolytes based onpoly(butoxymethylenenorbornene) for proton exchange membrane, Journal ofApplied Polymer Science,2012,123 (6), 3225-3233.

34. Xiaohui He*, Yueman Liu, Lu Chen, Yiwang Chen, Defu Chen, Ni(II) and Pd(II)Complexes Bearing Benzocyclohexan-ketoarylimine for Copolymerization ofNorbornene with 5-Norbornene-2-Carboxylic Ester, Journal of Polymer Science PartA: Polymer Chemistry,2012, 50 (22), 4695-4704.

35. Shufang Liu, Yiwang Chen*, Xiaohui He*, Lie Chen, Nie, Weihua Zhou, StableCrosslinked Vinyl Addition Type Polynorbornene Graft Copolymer Proton ExchangeMembranes, Journal of Applied Polymer Science,2011, 121(2), 1166-1175.

36. Yuepeng Xing, Yiwang Chen, Xiaohui He*, Copolymerization of norbornenewith methoxycarbonylnorbornene catalyzed by Ni{CF3C(O)CHC[N(naphthyl)]CH3}2/B(C6F5)3catalytic system and good processability for Dry/Wet phase inversion and electrospinning technique，Journal ofPolymer Science Part A: Polymer Chemistry,2011, 49(20), 4425-4432.

37. Kaiti Wang,Yiwang Chen, Xiaohui He*, Yueman Liu, Weihua Zhou, Ni(II) andPd(II) Complexes Bearing Novel Bis(b-ketoamino) Ligand and Their CatalyticActivity toward Copolymerization of Norbornene and 5-Norbornene-2-yl AcetateCombined with B(C6F5)3, Journal of Polymer Science Part A: Polymer Chemistry,2011, 49(15), 3304-3313.

38. Bin Yuan, Xiaohui He*, Yiwang Chen, Kaiti Wang, Preparation ofNanosilica/Polynorbornene Nanocomposite by Covalently ImmobilizedSilica-Supported Acetylacetonate Palladium(II) Dichloride Catalyst, macromoleculeschemistry and physics,2011, 212, 2378-2388.

39. Xiaohui He, Yingzheng Yao, Xiang Luo, Zhang Ling, Qing Wu, Ni(II)Complexes Bearing N,O-Chelate Ligands: Synthesis, Solid-Structure Characterizationand Reactivity toward the Polymerization of Polar Monomer , Organometallics ,2003, 22(24), 4952-4957.

国家发明专利

1．贺晓慧*，武斌，邹建华，温宇飞，主链含苯并降冰片烯结构的芳香族聚酰亚胺及制备方法，已公布。专利公开号：CN 113511980 A，2021.

2．贺晓慧*，温宇飞，邹建华，武斌，主链含苯并降冰片烯结构的聚酰亚胺及制备方法，已公布。专利公开号：CN 113388109 A，2021.

3．贺晓慧*，涂广水，含杂环六配位双水杨醛亚胺金属催化剂及制备方法和应用，已授权。专利公开号：CN 201910596830.8，2021.

4．贺晓慧*，朱传艺，一种[C^N^O]三齿螯合非对称过渡金属催化剂及其制备方法，已授权。专利公开号：CN 201910716477.2，2021.

5．霍平，贺晓慧*，刘万云，立体结构N,N-单配体金属催化剂及其制备方法，已授权。专利公开号：CN 105936659 B，2018.

6．贺晓慧, 刘菁胤，田建文，邓小丹，一种C-C 桥连[ONNO]-β-酮亚胺金属催化剂及制备方法，已授权。专利公开号：CN 105254786 A，2017.

7．贺晓慧，陈义旺，王凯悌，姚溢琼。一种立体结构N,O-双配体金属催化剂及制备方法，专利公开号：CN 102504056 B，2014.

8．贺晓慧，陈义旺，王凯悌，姚溢琼。一种立体结构N,O-单配体金属催化剂及制备方法，专利公开号：CN 102399323 B，2014

9．陈义旺，朱祥军，贺晓慧，王晓峰，原位酯交换低聚乳酸合成可降解性芳香/脂肪共聚酯的方法，已授权。专利号：CN 1817939 A,2007.

10．曹永沂，秦俊远，贺晓慧，邓仲明，邓幕健, 利用酯羰基伸缩振动峰测定聚酯多元醇羟值的方法, 已授权。专利号：CN101059432A,2007.

11．陈义旺、朱祥军、贺晓慧, 芳香族聚酯与脂肪族聚酯反应性共混合成可降解共聚酯的方法, 已授权。专利号：CN101016373A, 2007.

荣誉

2016江西省二级教授

2013江西省第十七批主要学科学术和技术带头人

2011高等学校中青年材料学科带头人

2009高等学校中青年材料学科带头人

2007江西省新世纪百千万人才

获奖

1.一等奖，江西省教育厅科技成果奖，晶调控异质结界面有机薄膜光伏电池，第五，2011年。

2.二等奖，江西省自然科学奖，材料微观尺度有序性控制与应用，第三，2007。

3.二等奖，江西省教育厅科技成果奖，材料微观尺度有序性控制与应用，第三，2007。

4.一等奖，江西省科学进步奖，DQ-50 环保型电气设备清洗剂研制，第二，2006。

联系方式

邮箱：hexiaohui@ncu.edu.cn

地址：江西省南昌市红谷滩新区学府大道999号，南昌大学物理与材料学院

QQ: 382899719

办公室：材料楼A500-C

欢迎对本课题组研究领域感兴趣的博士后、博士生、硕士生、本科同学加入。